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Olympiacos vs PSV prediction 04.11.2025 | Champions League

Olympiacos Piraeus

Olympiacos Piraeus

1 - 1

Elapsed: FT

Half time: 1 - 0

Full time: 1 - 1

Kick off:

Date:

PSV Eindhoven

PSV Eindhoven

match ended

The match has ended, you can view today's football predictions and football predictions for tomorrow.

  • Competition: Champions League
  • Date: Tuesday, 4th November, 2025
  • Kickoff: 20:00 UK / 21:00 CET
  • Venue: Georgios Karaiskakis Stadium (Piraeus)

On Tuesday evening, the Greek and the Netherlands champions will face off against each other in the fourth round of the Champions League, at Georgios Karaiskakis Stadium in Piraeus. The Greek team has yet to win a Champions League game, as they have only won one point in the first three rounds, and are eager to win points. Meanwhile, the Dutch team is in fantastic form and has also started the CL much better, considering they have won four points and are in 16th place.

Let's break down the match and find the best possible bet for the upcoming CL tie.

Olympiacos Piraeus vs PSV Eindhoven Head to Head (H2H) stats

  1. PSV Eindhoven

    2 : 1

    Olympiacos Piraeus

    Europa League

  2. Olympiacos Piraeus

    4 : 2

    PSV Eindhoven

    Europa League

  3. PSV Eindhoven

    4 : 0

    Olympiacos Piraeus

    Club Friendlies 1

The only time these two teams bet was back in 2021, in the Champions League 1/16 finals. That time, PSV won 2:1 at home and Olympiacos 4:2. The Greek team eventually advanced to the next phase on a 5:4 aggregate.

Besides those two matches, these teams also met in one friendly in 2018 when PSV won 4:0. 

Olympiacos Piraeus

Olympiacos team overview

Olympiacos had a great last season, winning the cup and the league title pretty dominantly as they left the second-placed Panathinaikos 16 points behind. In Europe League, they were decent, reaching the 1/8 Finals, but the impression was that they could have done more, considering they ultimately lost to Bodo/Glimt. 

For this year, the goal for the biggest Greek team remains pretty much the same - to win it all in the domestic competition and make a deep run in Europe. However, after winning just one point in the opening three CL games, the Red-Whites are more or less in a must-win position. Meanwhile, in the Greek Super League, the Red-Whites are in the top spot with 22 points in nine rounds, although with a game played more than PAOK. 

Last matches of Olympiacos Piraeus

  1. Olympiacos Piraeus

    2 : 1

    Aris

    Super League

  2. Olympiacos Piraeus

    5 : 0

    Volos NFC

    Greek Cup

  3. Olympiacos Piraeus

    2 : 0

    AEK Athens

    Super League

  4. FC Barcelona

    6 : 1

    Olympiacos Piraeus

    Champions League

  5. Larissa

    0 : 2

    Olympiacos Piraeus

    Super League

Olympiacos Piraeus lineup

Goalkeeper

  • 88

    Konstantinos Tzolakis

Defenders

  • 20

    Costinha

  • 45

    Panagiotis Retsos

  • 5

    Lorenzo Pirola

  • 70

    Bruno Onyemaechi

Midfielders

  • 96

    Christos Mouzakitis

  • 8

    Diogo Nascimento

  • 22

    Chiquinho

Forwards

  • 9

    Ayoub El Kaabi

  • 10

    Gelson Martins

  • 56

    Daniel Podence

PSV Eindhoven

PSV team overview

PSV managed to win their 26th league title last year after a magnificent end of the season where they won seven in a row and eventually secured the title one point away from the second-placed Ajax. This year, after ups and downs across the competitions, they are doing a really good job as they are currently on a five-game winning streak and an eight-game unbeaten run. Right now, they are second in the Eredivisie with 28 points from 11 rounds. They are on a level with the first-placed Feyenoord, but have a worse goal difference. 

After a 5:2 win over Sittard in the previous game, coach Peter Bosz spoke to the media. He said he enjoyed the first half but also noted the second half got "messy". The coach emphasized that they must be more efficient on the defensive end and expect better performances in the upcoming matches.

Last matches of PSV Eindhoven

  1. PSV Eindhoven

    5 : 2

    Fortuna Sittard

    Eredivisie

  2. Feyenoord

    2 : 3

    PSV Eindhoven

    Eredivisie

  3. PSV Eindhoven

    6 : 2

    Napoli

    Champions League

  4. PSV Eindhoven

    2 : 1

    Go Ahead Eagles

    Eredivisie

  5. PEC Zwolle

    0 : 4

    PSV Eindhoven

    Eredivisie

PSV Eindhoven lineup

Goalkeeper

  • 32

    Matej Kovar

Defenders

  • 8

    Sergiño Dest

  • 22

    Jerdy Schouten

  • 33

    Yarek Gasiorowski

  • 2

    Anass Salah-Eddine

Midfielders

  • 17

    Mauro Júnior

  • 34

    Ismael Saibari

  • 23

    Joey Veerman

Forwards

  • 27

    Dennis Man

  • 20

    Guus Til

  • 5

    Ivan Perišić

Prediction

Olympiacos have been excellent for this type of bet with three out of the last four games finishing with three or more goals. At home, they have been particularly efficient, scoring two or more goals in six out of seven games across the competitions - 86%. We expect another good offensive performance against a team that hasn't had a clean sheet in the past four games.

PSV won five in a row and have scored a total of 20 goals - four per game. Due to a good offensive performance, PSV went over 2.5 goals in all five of those matches. Moreover, PSV are a team that constantly goes over the mentioned line, considering we saw three or more goals in 12 out of 15 games across the competitions - 80%.

Additionally, all three h2h games ended with three or more goals. Considering all the above, an over 2.5 goals bet seems like the best possible bet for this Champions League tie.

4 Reasons why we should see three or more goals

  1. Olympiacos went over 2.5 goals in three out of the last four games
  2. Olympiacos scored two or more goals in six out of seven home games
  3. PSV went over 2.5 goals in 12 out of 15 games this season
  4. All three h2h games went over 2.5 goals

Main prediction Olympiacos Piraeus - PSV Eindhoven

Over 2.5 goals

Updated

clock
winrate

55% winrate

wins

3 wins in a row

Nikola has been betting for 10+ years and in the last couple of years he really improved his skills and made a lot of profit. He focuses mostly on football and basketball.

Olympiacos Piraeus vs PSV Eindhoven standings in Champions League

League Stage P W D L
G - A
GD Pts
1 FC Bayern München 4 4 0 0 14 - 3 +11 12
2 Arsenal 4 4 0 0 11 - 0 +11 12
3 Inter 4 4 0 0 11 - 1 +10 12
4 Manchester City 4 3 1 0 10 - 3 +7 10
5 Paris Saint Germain 4 3 0 1 14 - 5 +9 9
6 Newcastle United 4 3 0 1 10 - 2 +8 9
7 Real Madrid 4 3 0 1 8 - 2 +6 9
8 Liverpool 4 3 0 1 9 - 4 +5 9
9 Galatasaray 4 3 0 1 8 - 6 +2 9
10 Tottenham Hotspur 4 2 2 0 7 - 2 +5 8
11 FC Barcelona 4 2 1 1 12 - 7 +5 7
12 Chelsea 4 2 1 1 9 - 6 +3 7
13 Sporting CP 4 2 1 1 8 - 5 +3 7
14 Borussia Dortmund 4 2 1 1 13 - 11 +2 7
15 Qarabağ 4 2 1 1 8 - 7 +1 7
16 Atalanta 4 2 1 1 3 - 5 -2 7
17 Atlético Madrid 4 2 0 2 10 - 9 +1 6
18 PSV 4 1 2 1 9 - 7 +2 5
19 Monaco 4 1 2 1 4 - 6 -2 5
20 Pafos FC 4 1 2 1 2 - 5 -3 5
21 Bayer 04 Leverkusen 4 1 2 1 6 - 10 -4 5
22 Club Brugge 4 1 1 2 8 - 10 -2 4
23 Eintracht Frankfurt 4 1 1 2 7 - 11 -4 4
24 Napoli 4 1 1 2 4 - 9 -5 4
25 Olympique Marseille 4 1 0 3 6 - 5 +1 3
26 Juventus 4 0 3 1 7 - 8 -1 3
27 Athletic Club 4 1 0 3 4 - 9 -5 3
28 Union Saint-Gilloise 4 1 0 3 4 - 12 -8 3
29 Bodø / Glimt 4 0 2 2 5 - 8 -3 2
30 Slavia Praha 4 0 2 2 2 - 8 -6 2
31 Olympiacos F.C. 4 0 2 2 2 - 9 -7 2
32 Villarreal 4 0 1 3 2 - 6 -4 1
33 FC København 4 0 1 3 4 - 12 -8 1
34 Kairat 4 0 1 3 2 - 11 -9 1
35 Benfica 4 0 0 4 2 - 8 -6 0
36 Ajax 4 0 0 4 1 - 14 -13 0

Olympiacos vs PSV – FAQ

? Where to watch?

You can find the match officially on the Arena Sport channel.

? Who could be the goalscorer for Olympiacos?

Ayoub El Kaabi, who scored seven goals in 12 appearances this season.

? Who could be the goalscorer for PSV?

Ismael Saibari, who scored ten goals in 15 appearances this season.